Updated March 12, 2022:
Final report attached.
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Although Ca, Mg, and K are all exchangeable nutrients that are considered plant available, soil chemistry and plant root interactions result in different uptake and bioavailability. Within the soil, Ca and Mg can move with soil water or by diffusion, while the lower K concentrations do not readily move with soil water. The objectives of this study were to sample center pivots in their dry corners and irrigated regions and compare soil nutrient levels and nutrient uptake in the leaf tissue for potential. To do that, soybean fields 10 center pivots in Delaware were sampled in irrigated and dry corners. Upper leaf tissue and soil samples were obtained at the R2/R3 growth stage and tested for soil characteristics and nutrient contents.
Irrigated soybeans had higher concentrations of N, P, Fe, and Na in the upper leaf tissue, with K and Cu being slightly higher, but not statistically significant. This is not necessarily an issue for yield, as all measured leaf tissue nutrients were within their sufficiency ranges, except Ca which was just below the 0.8% threshold in both rainfed and irrigated soybeans.
Nitrogen also had no significant negative correlations in irrigated fields, with concentrations above threshold values (5.7%), so its possible N was not limited in these scenarios and would not produce negative correlations with other elements. This was not the case in rainfed samples, where N uptake was inversely correlated to Ca, Mg, and Al uptake, potentially due to stress when moisture was limited.
Greater Na concentrations in both irrigated soil and tissue samples was most likely related to salts in irrigation water, with Na having very few relationships to other elements in leaf tissue samples. Iron was also higher in irrigated tissue samples but had more correlations to tissue nutrients in rainfed samples. This may mean that Fe uptake occurred with higher soil moisture but was not related to any other nutrient uptake. Alternatively, Al uptake in rainfed beans may also reflect excess uptake, but under stressed conditions, where it positively correlated with many other tissue nutrients, but had no positive correlations with irrigated soybeans.
All these relationships are based on 2021 rainfall, which was sufficient for most of the early summer in Delaware, and not deficient until late July. It is certainly possible to have different relationships in doughtier years, which includes greater differences (lower N, P, and K in rainfed) between regions or fields with different moisture contents.