Updated April 27, 2021:
Polyurethanes are prominent sorts of polymeric materials that can be found within a plethora of commercial and industrial applications ranging from furniture, sound insulation, automotive, and coatings. The widespread use of polyurethanes can be attributed to the diverse range of synthetic feedstocks and preparatory methods used to manufacture both rigid and flexible foam derivatives, elastomers, and adhesives. Depending on the starting materials, the physical and mechanical properties of polyurethanes, e.g. density, flexibility, rigidity, etc., can be varied. The primary drawback of polyurethane foams is that they are overtly flammable.
In this project, we have shown that eco-friendly polyurethane foams using soybean oil can be prepared, and its flammability can be significantly reduced by adding cheap and green flame-retardants. Soybean oil was converted into polyol, a starting chemical for polyurethane, using a one step process that does not require high temperature, high pressure, and solvents.
The weight loss of the foams and burning time was significantly reduced even after adding only 0.93 % phosphorous in the foam. Additionally, no dripping was observed during the burn test, suggesting the high quality of the flame-retardant foams using soybean oil.